The scaffolding of a π-conjugated oligomer, namely terthiophene, is achieved by taking advantage of the self-assembly of a guanosine derivative into highly directional H-bonded networks. Reversible interconversion allows switching between ribbons and quartet-based assemblies in solution. The self-assembly of 1 on surfaces lead to large lamellae of straight ribbons, ultimately forming 1D conjugated arrays as prototypes of supramolecular nanowires.
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Spada et al. (2008) studied this question.
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