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Cyclopentadienyl ruthenium( ii ) thiosemicarbazone complexes with the formula [Ru(η 5 -C 5 H 5 )(Ac-tsc)PPh 3 ]·Cl ( 1 ), [Ru(η 5 -C 5 H 5 )(Ac-mtsc)PPh 3 ]·Cl ( 2 ), [Ru(η 5 -C 5 H 5 )(Ac-etsc)PPh 3 ]·Cl ( 3 ) and [Ru(η 5 -C 5 H 5 )(Ac-ptsc)PPh 3 ] ( 4 ) were synthesized and characterized by various spectroscopic techniques ( 1 H NMR, 13 C NMR, IR and UV-vis).
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Devagi et al. (2017) studied this question.
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