An iron (III) compound [Fe (thpu) (Hthpu) ] has exhibited spin transition behavior (T1/2↓=225 K and T1/2↓=239 K) with a thermal hysteresis loop (ΔT = 14 K). When the sample has been illuminated at 5 K, an increase in the dc susceptibility was observed. This suggests that the transition from the low-spin state to the high-spin state can be induced by illumination.
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Hayami et al. (2004) studied this question.
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