A chiral, nonracemic pentadentate pyridine bis(oxazoline) ligand forms unprecedented P-helical inorganic-organic hybrid polymers with cadmium halides. The one-dimensional chains consist of Lambda2-configured pentagonal-bipyramidal cadmium complexes with metal-centered chirality bridged by [CdX4]2- tetrahedra via shared halide atoms. In the solid state, the overall helicity exhibits strongly directed orientation parallel to the crystallographic axis a.
No takes yet. Share an insight, caveat, or question.
Seitz et al. (2004) studied this question.
Synapse has enriched 3 closely related papers on similar clinical questions. Consider them for comparative context: