Sol-gel TiO 2 decorated on eggshell nanocrystal as engineered adsorbents for removal of acid dye

Maged Abdeltawab El-Kemaryab, Ibrahim Mahmoud El-mehassebab, Kamel Rizq Shoueirb*, Shaymaa Elsayed El-Shafeyc, Ola Ibrahim El-Shafeyc, Hind Abdullah Aljohanid & Rasha Refaat Fouadea Faculty of Science, Kafrelsheikh University, Kafrelsheikh, Egyptb Chemistry Department, Institute of Nanoscience & Nanotechnology, Kafrelsheikh University, Kafrelsheikh, Egyptc Surface Chemistry and Catalysis laboratory, Physical Chemistry Department, National Research Center, NRC, Dokki, Cairo, Egyptd Department of Chemistry, University College at Alwajh, University of Tabuk, Tabuk, Saudi Arabiae Marine Pollution Department, National Institute of Oceanography and Fisheries (NIOF), Hurghada, EgyptCONTACT Kamel Rizq Shoueir kameltag@yahoo.com Chemistry Department, Institute of Nanoscience & Nanotechnology, Kafrelsheikh University, 33516 Kafr Elsheikh, Egypt.Color versions of one or more of the figures in the article can be found online at www.tandfonline.com/ldis.ABSTRACTCalcined eggshell (CES) food residue was modified by depositing sol-gel titanium dioxide (TiO2) nanoparticles with narrow size distribution onto it through in situ precipitation and a novel hybrid nano biosorbent, namely TiO2-CES, was obtained. The deposition was characterized and the TiO2-CES nano network was used for efficient adsorption of single azo class anionic dye acid red nylon 57 (AN57) from aqueous solutions and the adsorption was pH dependent. Lower pH favored the sorption at the tested different pHs of 1.0–8.0. The calcination temperature had a cogent influence on the adsorption process. The sorption process reached equilibrium within 40 min, and the mathematical models were positively verified and could be described by a pseudo-second-order pattern, while equilibrium was described with Langmuir-type equation. In addition, the reusability study has proven that 0.5 M HNO3 was efficient enough to desorb AN57 from the hybrid nano sorbent. All results validated that TiO2-CES is Eco-Friendly adsorbent material practical treatment of dyes contaminated water.