Answers are grounded in this paper and cite their sources.
A global analysis of the kinetic results relating to a model reaction of epoxy‐carboxy polycondensation is reported. The model is the reaction of benzoic acid with 1‐phenoxy‐2,3‐epoxypropane carried out in the presence of N,N‐dimethyldodecylamine as catalyst. The hypothesis concerning the contribution of two competitive ractions as suggested in the two preceding parts of this series is subjected to a mathematical treatement. This allowed the determination of the rate constants of each reaction. All the kinetic characteristics obtained in a broad range of experimental conditions fit the reaction scheme, which is described in detail. Exceptions are found for borderline cases. The rate constants of the reaction of the classical dependence on dielectric constant and temperature. Activation parameters of each reaction are reported.
No takes yet. Share an insight, caveat, or question.
Madec et al. (1983) studied this question.
Synapse has enriched 10 related papers. Consider them for comparative context: