Cleavage of the CC bond by CpCo(CO)2 provides the most facile entry conceivable to biscarbyne clusters such as (1). In this reaction bis(trimethylsilyl)butadiyne and -hexatriyne form. inter alia, complexes with two cluster units. All these complexes are possibly suitable as models for H/D exchange reactions and hydroformylation.
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Fritch et al. (1980) studied this question.
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