⌘+K

Pulse Explore Communities Researchers Journals

Home Communities Explore

January 1, 1986Journal of the Chemical Society Perkin Transactions 2

Descriptions and analyses of guest cavity size and shape in a new family of helical tubuland inclusion crystals

Ian Dance Roger Bishop M.L. Scudder

View at Publisher

Ask AI

Bookmark

Share

Abstract

The crystal structures of exo-2,exo-6-dihydroxy-2,6-dimethylbicyclo[3.3.1]nonane, syn-2,syn-7-dihydroxy-2,7-dimethyltricyclo[4.3.1.113,8]undecane, anti-2,anti-7-dihydroxy-2,7-dimethyltricyclo-[4.3.1.13,8]undecane, and syn-2,syn-8-dihydroxy-2,8-dimethyltricyclo[5.3.1.13,9]dodecane, four geometrically different instances of the helical tubuland inclusion lattice, are analysed in terms of the structural variables of the host molecules and the lattice, which allow substantial variations in the sizes and shapes of the inclusion cavities. The cavity dimensions are described in detail.

Discussion

No takes yet. Share an insight, caveat, or question.

Cite This Study

DANCE et al. (1986) studied this question.

synapsesocial.com/papers/6acb1c61c37a5c3e85124bf7 https://doi.org/10.1039/p29860001309

View at Publisher

Ask AI

Bookmark

Share

Keep reading

Synapse has enriched 5 related papers. Consider them for comparative context:

1Stereoelectronic substituent effects on intramolecular H-bonding in crowded o-anisic acidsJournal of the Chemical Society Perkin Transactions 2 · 2002
25-Diisopropoxyphosphoryl-5-methyl-1-pyrroline N-oxide, DIPPMPO, a crystalline analog of the nitrone DEPMPO: synthesis and spin trapping propertiesElectronic supplementary information (ESI) available: Tables of crystallographic data. See http://www.rsc.org/suppdata/p2/b2/b206909c/Journal of the Chemical Society Perkin Transactions 2 · 2002
34,4-p-Biphenyl bis-phosphinidene: generation of a bis-W(CO)5 complex and ab initio calculation of its electronic structureJournal of the Chemical Society Perkin Transactions 2 · 2002
4Calculation of Abraham descriptors from experimental data from seven HPLC systems; evaluation of five different methods of calculationElectronic supplementary information (ESI) available: Tables S1 to S5. See http://www.rsc.org/suppdata/p2/b2/b206927j/Journal of the Chemical Society Perkin Transactions 2 · 2002
5Solution phase, solid state and computational structural studies of the 2-aryl-3-bromoquinolin-4(1H)-one derivatives1Journal of the Chemical Society Perkin Transactions 2 · 2002

EPR detection of the unstable tert-butylperoxyl radical adduct of the spin trap 5,5-dimethyl-1-pyrroline N-oxide: a combined spin-trapping and continuous-flow investigationJournal of the Chemical Society Perkin Transactions 2 · 2002
Steric and electronic effects on the mechanism of nucleophilic substitution (SNAr) reactions of some phenyl 2,4,6-trinitrophenyl ethers with aniline and N-methylaniline in acetonitrile and in dimethyl sulfoxideJournal of the Chemical Society Perkin Transactions 2 · 2002
1,3-Dipolar additions involving allenes: A density functional study of concerted and stepwise mechanismsElectronic supplementary information (ESI) available: Cartesian co-ordinates of all the structures with their computed total energies. See http://www.rsc.org/suppdata/p2/b2/b206470gJournal of the Chemical Society Perkin Transactions 2 · 2002
Hydrogen abstraction from ethylbenzene by imide-N-oxyl radicals with and without O2: a DFT theoretical studyJournal of the Chemical Society Perkin Transactions 2 · 2002
N-Nitrosamide-mediated Ritter-type reactions.Journal of the Chemical Society Perkin Transactions 2 · 2002

More from Journal of the Chemical Society Perkin Transactions 2