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Manganese tetraphenylporphyrin supported on nano- TiO2 has been synthesized and structurally characterized. It has been shown to have excellent catalytic activity for the aerobic oxidation of α-pinene. Experimental results showed that this much-enhanced activity could arise from possible co-catalysis between metalloporphyrin and the nano- TiO2 support. The catalyst can be reused several times with minor loss to its catalytic activity.
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Yang et al. (2009) studied this question.
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