An extension of the dimensionless treatment of Troe is developed for fitting falloff data from unimolecular and recombination reactions. This method using dimensionless parametrizations derived from accurate numerical solutions of the master equation for system with any type of activated complex and energy transfer probability distribution, is as easily implemented as Troe's method, and allows global fitting of an entire set of pressure‐ and temperature‐dependent rate coefficients.
No takes yet. Share an insight, caveat, or question.
Poole et al. (1994) studied this question.
Synapse has enriched 2 closely related papers on similar clinical questions. Consider them for comparative context: