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The electrochemical behavior of copper and zinc in neutral (рН 7.4) borate buffer solution with addition of 0.5 M NaCl and the effect of 2-merсaptobenzothiazole (MBT) on the electrochemical processes and adsorption on these metals has been studied by means of electrochemistry and X-ray photoelectron spectroscopy (XPS).The formation of MBTmetal cation complex films on copper and zinc surface has been shown.The effect of corrosive media composition and time-dependent relations of nanoscale film growth on the surface of the metals investigated have been determined.It was assumed that adsorbed MBT anion forms M(MBT) х , a polymeric complex where M = Cu + (x = 1) or Zn 2+ (x = 2).
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Arkhipushkin et al. (2014) studied this question.
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