Enhancement of ferromagnetism by Cr doping in Ni-Mn-Cr-Sb Heusler alloys

A series of Mn rich Ni50Mn37−xCrxSb13 Heusler alloys have been investigated by dc magnetization and electrical resistivity measurements. Due to the weakening of the Ni-Mn hybridization, the martensitic transition shifts to lower temperatures with increasing Cr concentration, while the saturation magnetization at 5 K increases. The magnetoresistance and exchange bias properties are dramatically suppressed with increasing Cr concentration. The observed behaviors suggest that substitution of Cr for Mn in Ni50Mn37−xCrxSb13 Heusler alloys not only destabilizes the martensitic phase but also enhances ferromagnetism in the system. The possible mechanisms responsible for the observed behavior are discussed.