The published data on the structures and properties of crystalline actinide compounds having mutually coordinated AnO2+ or AnO22+ cations as structural elements are surveyed. This cation—cation interaction is an important structure-forming factor for many crystalline compounds of Np(V) and U(VI). It strongly affects their UV-Vis and IR spectra as well as other properties. Differences and similarities between the cation—cation interactions of actinide ions in solutions and crystals are discussed. The bibliography includes 114 references.
No takes yet. Share an insight, caveat, or question.
Krot et al. (2004) studied this question.
Synapse has enriched 5 related papers. Consider them for comparative context: