Twenty-one lines of the Schüler band of ND4, previously observed in emission from high pressure ND3 discharges and assigned to a transition between excited states, have been observed in absorption in the Hg-photosensitized reaction of ND3. In this system ND4 is probably formed by a reaction of the HgND*3 exciplex. The observed transition originates from either the 3s, 2A1 ground state or the 3p, 2F2 excited state, the former being more likely.
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Whittaker et al. (1984) studied this question.
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