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The molecular vibrations of dibenzene chromium are analyzed in terms of the eclipsed 25 atomic model of symmetry D6h with planar ligands. A complete set of symmetry coordinates is constructed and based almost entirely on conventional types of valence coordinates. A harmonic force field is given, and is used to calculate the vibrational frequencies, mean amplitudes of vibration, and perpendicular amplitude correction coefficients for (C6H6)2Cr and (C6D6)2Cr.
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Cyvin et al. (1971) studied this question.
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