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New multi-sulfur 1,2-dithiolene complexes in which the 1,2-dithiolene moiety is extended by incorporating heterorings have been prepared and characterized by IR spectroscopy, X-ray diffraction method, and cyclic voltammetry. Partial oxidation of these complexes are expected to provide the multi-dimensional molecular conductors. Electrochemical properties of these complexes are compared with those of the dmit-complexes (dmit=2-thioxo-1,3-dithiole-4,5-dithiolate).
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Kato et al. (1986) studied this question.
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