The construction of alkali metal-based metal–organic frameworks (AMOFs) with permanent porosity represents a notable challenge. Here we report a novel sodium-based MOF, designated HIAM-113, built on tetranuclear Na4 clusters and a tetracarboxylate linker. HIAM-113 features high structural robustness and one-dimensional channels that are optimal for size-sieving separation of hexane isomers.
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Miao et al. (2026) studied this question.
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