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Tris(trimethyl)silyl compounds of all GroupIIIB metals are known now that the synthesis of Ga(SiMe3)3 has been accomplished. The tetrahydrofuran adduct (1) initially obtained can be freed from solvent by sublimation in a high vacuum. Ga(SiMe3)3 resembles the indium derivative more closely than the (associating) aluminum derivative. equation image
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Rösch et al. (1980) studied this question.
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