Dielectric studies of the hexatic B-smectic A and crystal B-smectic A transitions

Static dielectric constants, ∊∥ and ∊⊥ as well as the low frequency dielectric dispersion of ∊∥ have been studied in the vicinity of the hexatic B-smectic A transition in n-hexyl-4'-pentyloxybiphenyl-4-carboxylate (65OBC) and n-butyl-4'-hexyloxybiphenyl-4-carboxylate (46OBC) and also near the crystal B-smectic A transition in n-(4-n-butyloxybenzylidene)-4-n-octylaniline (4O. 8). While the behaviour of the dielectric anisotropy is essentially similar for both transitions, the dispersion results show significant differences.