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A compilation of data that concern the point defect parameters in LiF is presented. It is shown that the entropy (s) scales with the enthalpy (h) for the following processes: Schottky formation, free cation migration and (re) orientation of the 'Mg 2+ -cation vacancy' dipole. The ratio s/h is governed only by well known macroscopic properties of the bulk solid. Furthermore, the ratio of the defect volume and the defect energy is discussed.
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Lazaridou et al. (1985) studied this question.
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