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The oxidative addition of acetic or formic acid to Pd0(PPh3)4 in DMF affords a cationic palladium(II) hydride, trans-HPd(PPh3)2(DMF)+, with acetate or formate as the counter anion. The two reactions are reversible. The equilibrium and kinetic constants of the oxidative additions have been determined.
Amatore et al. (Tue,) studied this question.
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