What question did this study set out to answer?

To synthesize and characterize the monomeric high-valent ruthenium(IV)-oxo complex [(bpy)2(py)Ru:O]2+.

May 1, 1978Journal of the American Chemical Society117 citations

Oxobis(2,2'-bipyridine)pyridineruthenium(IV) ion, (bpy)2(py)Ru:O2+

Key Points

To synthesize and characterize the monomeric high-valent ruthenium(IV)-oxo complex [(bpy)2(py)Ru:O]2+.
Synthesized the [(bpy)2(py)Ru:O]2+ complex coordinating 2,2'-bipyridine and pyridine ligands to a ruthenium center.
Characterized the spectroscopic and electrochemical properties associated with the ruthenium(IV) oxidation state.
Demonstrated the isolation and stability of a discrete monomeric ruthenium(IV)-oxo cation in solution.
Showed that the terminal oxo ligand stabilizes the high formal oxidation state through metal-ligand multiple bonding.

Abstract

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTOxobis(2,2'-bipyridine)pyridineruthenium(IV) ion, (bpy)2(py)Ru:O2+Bruce A. Moyer and Thomas J. MeyerCite this: J. Am. Chem. Soc. 1978, 100, 11, 3601–3603Publication Date (Print):May 1, 1978Publication History Published online1 May 2002Published inissue 1 May 1978https://pubs.acs.org/doi/10.1021/ja00479a054https://doi.org/10.1021/ja00479a054research-articleACS PublicationsRequest reuse permissionsArticle Views938Altmetric-Citations104LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts

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