A Modular and Size‐Selective Synthesis of nCycloparaphenylenes: A Step toward the Selective Synthesis of n,n Single‐Walled Carbon Nanotubes

A modular strategy served in the size-selective syntheses of 14-, 15-, and 16cycloparaphenylenes (CPPs). A Suzuki–Miyaura coupling was used to assemble a terphenyl-equivalent, L-shaped cis-1,4-diphenylcyclohexane unit and a linear benzene/biphenyl unit in a 3+1+3 or 3+2+3 mode to give U-shaped septi- and octiphenyl units. The cyclizative dimerization of these U-shaped units and subsequent aromatization yielded the CPPs. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.