The Effect of High Pressure on MOF‐5: Guest‐Induced Modification of Pore Size and Content at High Pressure

Grace under pressure: In the first high-pressure crystallographic study on the metal–organic framework MOF-5, increasing pressure initially results in the pressure-transmitting fluid being squeezed into the pores. Further pressure increase causes a large reduction in pore content as solvent is evacuated from the pores, until a complete loss of crystallinity is observed at pressures above 3.2 GPa. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.