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Although enantioselective catalysis under thermal conditions has been well established over the last few decades, the enantioselective catalysis of photochemical reactions is still a challenging task resulting from the complex enantiotopic face differentiation in the photoexcited state. Recently, remarkable achievements have been reported by a synergistic combination of organocatalysis and photocatalysis, which have led to the expedient construction of a diverse range of enantioenriched molecules which are generally not easily accessible under thermal conditions. In this tutorial review, we summarize and highlight the most significant advances in iminium and enamine catalysis of enantioselective photochemical reactions, with an emphasis on catalytic modes and reaction types.
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You‐Quan Zou
Fabian M. Hörmann
Thorsten Bach
Chemical Society Reviews
Technical University of Munich
Max Planck Computing and Data Facility
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Zou et al. (Mon,) studied this question.
www.synapsesocial.com/papers/69d83abff4e559c61eae311e — DOI: https://doi.org/10.1039/c7cs00509a
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