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reaction: see text Palladium complexes (1 and 2) were immobilized in ionic liquids, and their applications to catalytic asymmetric fluorination and Michael reaction of beta-ketoesters were successfully demonstrated. This immobilization enabled the reuse of the catalysts no less than 10 times in fluorination and 5 times in Michael reaction with levels of efficiency comparable to those obtained in usual organic solvents.
Hamashima et al. (2003) studied this question.
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