December 3, 2001

Enantioseparation of Racemic Organic Molecules by a Zeolite Analogue This work was supported by The Major State Basic Research Development Program (Grant No. G2000077500), the National Natural Science Foundation of China, the Camille Dreyfus Teacher–Scholar Program, the National Science Foundation of the USA (CHE-9904338), and the University of Tennessee SARIF EPPE Fund.

RXRen‐Gen XiongUniversiti Sains Malaysia XYXiao‐Zeng YouNorthwest University BABrendan F. AbrahamsThe University of Melbourne

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Abstract

Selective inclusion of (S)-2-butanol and (S)-2-methyl-1-butanol from their racemic mixtures in 98.2 and 98.4 % ee, respectively, is obtained with the robust 3D enantiopure hybrid organic–inorganic zeolite analogue Cd(QA)2 (see scheme), which is formed by self-assembly of chiral quitenine (HQA) with Cd(OH)2.

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