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Abstract The oxide surface structure plays a vital role in controlling and utilizing the emergent phenomena occurring at the interface of nanoarchitecture. A complete understanding of ternary oxide surfaces remains challenging due to complex surface reconstructions in various chemical and physical environments. Here a thermodynamic framework is developed to treat the stability of ternary oxide surfaces with finite temperature and chemical environments. Strontium titanate, as a representative ternary oxide, is used to establish the complete energy landscape of SrTiO 3 (001) surface. The complete mapping yields a comprehensive understanding of various stable SrTiO 3 surfaces with finite temperature and chemical potential or vapor pressure of the constituents, i.e., Sr (or Ti) metal and oxygen. This treatment also reveals a stable surface unknown yet with SrTi 2 O 3 stoichiometry, which unveils the missing link between numerous previous experimental observations and the current understanding of SrTiO 3 surface. Interestingly, the new surface shows an anisotropic surface‐localized metallic state originating from the characteristic surface structure. The findings would provide a viable way to understand ternary oxide surfaces and further utilize SrTiO 3 surfaces for oxide nanoarchitectures.
Rahman et al. (Thu,) studied this question.