Roaming-controlled formation of dimethyl ether and methanol: role of nonequilibrium dynamics and integrability

Key Points

• Roaming leads to the formation of dimethyl ether from methanol due to ionization processes.
• Nonequilibrium energy partitioning is crucial, significantly suppressing energy exchange between species.
• This process is indicative of a quasi-integrable regime, impacting the overall dynamics observed.
• The electron recombination process plays a significant role in the transformation occurring in the clusters.