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May 8, 2026Open Access

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Key Points

The research aims to convert poly(-caprolactone) into azepane using a titanium oxide-supported platinum catalyst.
Direct conversion of poly(-caprolactone) into azepane via reductive ammonolysis
Utilization of a reusable Pt/TiO2 catalyst
Investigation of catalytic performance based on the synergistic roles of TiO2 and Pt
High catalytic performance observed with the Pt/TiO2 catalyst
TiO2 facilitates depolymerization while Pt nanoparticles activate H2
Effective conversion leads to azepane formation with sustainable catalyst utilization

Abstract

Upcycling poly(-caprolactone) into azepane via reductive ammonolysis over a titanium oxide-supported platinum catalystThis work highlights the direct conversion of poly (-caprolactone) into azepane, a seven-membered N-heterocycle, using a reusable Pt/TiO 2 catalyst.The high catalytic performance is attributed to the synergistic roles of TiO 2 and Pt nanoparticles: TiO 2 promotes depolymerization, while Pt nanoparticles activate H 2 .

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Cite this study

A Thu, study studied this question.

www.synapsesocial.com/papers/69fd7d4abfa21ec5bbf05e11 — DOI: https://doi.org/10.1039/d6gc90090a

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