To address hydrogen separation from hydrogen-blended natural gas, this work develops a mathematical model for a novel thermal-transpiration-effect-based circulating-flow gas separator according to the Navier–Stokes equations, following the joint modification with velocity-slip and temperature-jump boundary conditions, and a binary gas diffusion model derived from the Maxwell–Stefan equations. The model is then used to investigate the component transport and flow of a CH4-H2 mixture at the slip flow regime. The average hydrogen mole fraction in the component enrichment zone increases monotonically as the temperature difference increases, reaching 0.429 at a hot channel temperature of 400 K. An optimum inlet gas velocity of 0.93 m/s is identified to achieve the maximum average hydrogen mole fraction in the enrichment zone. In addition, decreasing the microchannel diameter enhances the hydrogen enrichment performance, with the average hydrogen mole fraction reaching 0.578 at a microchannel diameter of 1 μm whereas increasing the microchannel diameter improves the product gas flow rate, indicating a trade-off between separation performance and processing capacity. These insights provide guidance for understanding the component transport mechanism and for the preliminary design of this type of gas separator for hydrogen separation applications.
Yang et al. (Sat,) studied this question.