The aim of this work was to investigate the evolutionary mechanisms of an artificial sedimentary agglomerate formed by cathodic polarization in natural seawater during its abandonment to a natural environment. Previous studies indicate that the mineralogical evolution of the material is controlled by kinetic factors and/or the local precipitation of aragonite on the brucite surface. However, the observation of the precipitation of metastable phase precipitation during the initial immersion of this material (in powder form) has suggested the possibility of a more complex mechanism. The present study builds upon previous experimental work and includes thermogravimetric analysis and infrared spectrometry. The results are analyzed using numerical experimentation to evaluate the proposed hypotheses. Findings show that the transformation mechanism is characterized by the precipitation of metastable calcium carbonate phases. Under supersaturation conditions, these hydrated phases form on the brucite surface, limiting the mineral’s contact with the solution. The subsequent transformation of these amorphous phases into aragonite further reduces brucite–solution interaction, which explains the persistence of brucite both in the residual powder after 120 h of immersion and in the consolidated material after more than 20 years of exposure to natural seawater.
Zadi et al. (Thu,) studied this question.