What question did this study set out to answer?

Investigate how group 13 elements affect the reactivity of G13–As–Ge imine analogues in 1,3-addition reactions.

January 18, 2026RSC Advances0 citationsOpen Access

Understanding the influence of group 13 elements on the reactivity of G13–As–Ge imine analogues in 1,3-addition with methyl iodide

Key Points

Investigate how group 13 elements affect the reactivity of G13–As–Ge imine analogues in 1,3-addition reactions.
Analyzed the G13–As–Ge frameworks
Studied the effects of group 13 elements
Evaluated reaction rates with methyl iodide
Angular contraction enhances orbital interactions with CH3I
Reaction accelerates due to lower energy barriers

Abstract

The pronounced relativistic effects associated with heavier group 13 element induce angular contraction in G13–As–Ge frameworks, thereby facilitating superior orbital interaction with CH 3 I and accelerating the reaction by reducing the energy barrier.

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