Scanning Electrochemical Microscopy represents one of the most advanced high-resolution techniques that enables detailed monitoring of electrochemical processes, with a particular focus on corrosion phenomena. Scanning Electrochemical Microscopy has become an indispensable tool in studying the behavior and degradation of protective coatings exposed to aggressive environmental conditions. This technique allows researchers to precisely track local electrochemical reactions on material surfaces, providing valuable information about the stability and effectiveness of coatings. Scanning Electrochemical Microscopy enables the detection of localized current variations in the pA–nA range, allowing the identification of microdefects with nanometric width. In this paper, the basic principles of Scanning Electrochemical Microscopy operation are first presented, including a description of the device. The method of scanning the electrode is discussed through the modes and their interpretation of the obtained data for systems with protective anticorrosive coatings. Furthermore, Scanning Electrochemical Microscopy techniques enable a detailed study of the mechanisms and kinetics of new, modified coatings, which is especially significant in the case of nanoparticle-enriched coatings. Such modifications often enhance the protective properties of materials, and Scanning Electrochemical Microscopy allows monitoring of their performance under real conditions, providing insight into local electrochemical changes that are otherwise difficult to detect with standard methods. Special attention is given to the challenges researchers may encounter during experiments, such as calibration prior to measurement, interpretation of input parameters, and signal analysis. This paper aims to provide a comprehensive overview of the capabilities and limitations of Scanning Electrochemical Microscopy (SECM), emphasizing its importance as a tool for the development and optimization of new, high-performance coatings for industrial applications and scientific research.
Samardžija et al. (Thu,) studied this question.