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Shedding light on overpotentials and underpotentials in (photo)electrochemical reactions | Synapse

February 21, 2026Chemical Society Reviews6 citations

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Shedding light on overpotentials and underpotentials in (photo)electrochemical reactions

DNDaiki NishioriArizona State University ECEdgar A. Reyes CruzArizona State University LHLillian K. HensleighArizona State University

Key Points

The research aims to explore the significance of overpotentials in both electrochemical and photoelectrochemical reactions.
Overview of existing literature on overpotentials
Comparison of electrochemical and photoelectrochemical reactions
Analysis of enthalpic and entropic contributions
Highlights the critical role of overpotentials in catalytic performance
Differentiates between enthalpic and entropic contributions in reactions

Abstract

Overpotential requirements are central to catalytic performance. This article provides an overview of overpotentials in electrochemical versus photoelectrochemical reactions and considers their enthalpic versus entropic contributions.

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Cite This Study

Nishiori et al. (Thu,) studied this question.

synapsesocial.com/papers/69994cdf873532290d021b9c https://doi.org/https://doi.org/10.1039/d4cs00695j