What question did this study set out to answer?

The aim is to synthesize and characterize a new manganese-containing carborane complex.

February 26, 2026Russian Journal of General Chemistry1 citations

Oxonium Derivative of Manganacarborane 1,1,1-(CO)3-6-C4H8O-isonido-1,2,4-MnC2B8H9

Q: What does this research mean for the field?

The reaction of the anionic complex [1,1,1-(CO)3-isonido-1,2,4-MnC2B8H10]–X+ with THF leads to the formation of the neutral complex 1,1,1-(CO)3-6-C4H8O-isonido-1,2,4-MnC2B8H9. Novelty: ClaimNovelty.NOVEL_FINDING. Consensus alignment: ConsensusAlignment.NEUTRAL.

EBE. V. BalagurovaA. N. Nesmeyanov Institute of Organoelement Compounds IGIvan A. GodovikovA. N. Nesmeyanov Institute of Organoelement Compounds

Key Points

The aim is to synthesize and characterize a new manganese-containing carborane complex.
Conducted reactions of anionic complexes with THF and initiators.
Utilized BF3·Et2O, H2SO4, and AlCl3 as chemical initiators.
Analyzed the structure using multinuclear NMR, IR spectroscopy, and elemental analysis.
Successfully formed a neutral complex 1,1,1-(CO)3-6-C4H8O-isonido-1,2,4-MnC2B8H9.
Confirmed the presence of THF at the boron atom in the B6 position.
Characterization techniques validated the structure of the new compound.

Abstract

The reaction of the anionic complex 1,1,1-(CO)3-isonido-1,2,4-MnC2B8H10–X+ (X = Na, PPN+, tmndH+) with THF in the presence of initiators (BF3·Et2O, H2SO4, AlCl3) leads to the formation of the neutral complex 1,1,1-(CO)3-6-C4H8O-isonido-1,2,4-MnC2B8H9 with a THF molecule at the boron atom in the B6 position of the carborane ligand. Structure of the complex was established by multinuclear NMR, IR spectroscopy, and elemental analysis methods.

问 AI

Bookmark

View Full Paper