This study systematically investigates the influence of annealing time on the microstructure and mechanical properties of a (CoCrNi)93.5Al3Ti3C0.5 medium-entropy alloy. Following hot-rolling, the alloy was subjected to annealing treatments at 900 °C for 10 min (HA900-10) and 60 min (HA900-60). Microstructural characterization revealed that both alloys contained three types of precipitates: intergranular M23C6 and MC-type carbides, as well as γ′ phase. The HA900-10 specimen exhibited a low degree of recrystallization, whereas prolonged annealing promoted partial recrystallization, leading to the formation of a slightly heterogeneous structure (HA900-60). Additionally, the extended annealing facilitated the intragranular precipitation of nanoscale γ′ phase. Room-temperature tensile tests demonstrated that the HA900-10 and HA900-60 specimens achieved yield strengths of 1276 MPa and 1202 MPa, with total elongations reaching 26% and 28%, respectively. Quantitative strengthening analysis indicated that the strength of HA900-10 primarily originated from dislocation and grain boundary strengthening. For HA900-60, an additional significant contribution arose from the dislocation shearing mechanism induced by the intragranular γ′ precipitates. Analysis of the deformation mechanisms revealed that planar slip, assisted by the formation of stacking faults, dominated the room-temperature deformation, thereby ensuring sustained work-hardening capacity. This research provides a theoretical foundation for tailoring the microstructure and properties of multi-phase medium-entropy alloys through annealing process control.
Zhang et al. (Sat,) studied this question.