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March 4, 2026The Analyst0 citations

Lighting Up Hypochlorous Acid through C(sp2)-H Hydroxylation with a Solvatochromic Organoiridium(III) Complex-based Probe

SKSnehadrinarayan KhatuaBSBhaskar SenJGJogat Gogoi

Key Points

  • This research aims to achieve selective detection of hypochlorous acid using a specific organometallic complex.
  • Utilized a solvatochromic cyclometalated Ir(III) complex for detection.
  • Employed a unique mechanism for C(sp2)-H hydroxylation.
  • Conducted experiments to evaluate selectivity and sensitivity of the complex.
  • Demonstrated high selectivity for hypochlorous acid over other reactive species.
  • Achieved effective detection through C(sp2)-H hydroxylation mechanism.

Abstract

Herein, we report the highly selective detection of the reactive oxygen species hypochlorous acid (HOCl) using a solvatochromic cyclometalated Ir(III) complex through a unique C(sp2)-H hydroxylation mechanism. The complex, Ir-1,...

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Cite This Study

Khatua et al. (2026) studied this question.

synapsesocial.com/papers/69a7cd2ad48f933b5eed94f4https://doi.org/10.1039/d6an00002a
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