Contents list

Key Points

• The aim is to explore the synthesis of bent metallacycles through mechanochemical methods and their catalytic properties.
• Utilized mechanochemical strategies for synthesis
• Examined structural properties of bent metallacycles
• Evaluated catalysis under confined conditions
• Successfully synthesized bent metallacycles using mechanochemistry
• Demonstrated enhanced catalytic activity compared to traditional methods
• Showed potential for confinement effects in catalytic processes