What does this research mean for the field?

Two new solvatomorphs of a tetranuclear Fe(III) cluster based on sulfonylcalix[4]arene exhibit unique spin properties as determined by 57Fe Mössbauer spectroscopy. Novelty: ClaimNovelty.NOVEL_FINDING. Consensus alignment: ConsensusAlignment.NEUTRAL.

What question did this study set out to answer?

This research aims to explore the solvatomorphism and spin properties of a specific iron cluster compound.

March 16, 2026Journal of Structural Chemistry0 citations

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The Study of Solvatomorphism and Spin Properties of the Cluster Based on Sulfonylcalix4Arene

AOA. S. Ovsyannikov AIA. A. Iova YSYu. V. Strel’nikova

Key Points

This research aims to explore the solvatomorphism and spin properties of a specific iron cluster compound.
Synthesis of two new solvatomorphs of the tetranuclear Fe(III) cluster.
Determination of structures using single crystal X-ray diffraction.
Analysis of spin properties using 57Fe Mössbauer spectroscopy.
Two distinct solvatomorphs were successfully synthesized.
Unique structural features were identified through X-ray diffraction.
Mössbauer spectroscopy revealed novel spin properties of the complexes.

Abstract

Two new solvatomorphs of the tetranuclear Fe(III) cluster based on sulfonylcalix4arene are synthesized and their structures are determined by single crystal X-ray diffraction. The spin properties of the obtained complexes are studied for the first time by 57Fe Mössbauer spectroscopy.

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The Study of Solvatomorphism and Spin Properties of the Cluster Based on Sulfonylcalix4Arene

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