Conformationally Locked BODIPY Donor–Acceptor Dyads: Charge Separation and Recombination across a 2.2.2Bicyclooctane Spacer

Key Points

• The research aims to understand how geometry affects charge separation and recombination in donor-acceptor systems.
• Investigation of excited-state dynamics in D-A dyads
• Analysis of charge-separated states
• Study of intramolecular rotations and vibrations
• Identified challenges in controlling excited-state dynamics
• Demonstrated effects of molecular geometry on charge dynamics
• Clarified the role of conformational locking in charge behavior