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April 24, 2003Journal of Natural Products73 citations

Structure Reassignment of the Fungal Metabolite TAEMC161 as the Phytotoxin Viridiol

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PWPeter WipfAKAngela D. Kerekes

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Abstract

Two-dimensional NMR analyses including HMBC, NOESY, and ROESY as well as 1D NOE experiments led to a reassignment of the structure of the recently identified Trichoderma hamatum metabolite TAEMC161 (1) as the previously known viridiol (2). In addition, GIAO-calculated (13)C NMR chemical shifts of 1 and 2 provided strong support for the revised structure.

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Wipf et al. (2003) studied this question.

synapsesocial.com/papers/69d8b181d2f7327e70ae4005https://doi.org/10.1021/np0300277
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