The Diamagnetism of the Free Electron

In a recent paper Landau has shown that, when electrons are moving freely in a magnetic field, they exhibit, in addition to the paramagnetic effect of their spin, a diamagnetic effect due to their motion. This result is rather unexpected, since it is quite contrary to the classical case. There it might appear as though the circles described by the electrons must produce a magnetic moment, but the error was long ago pointed out by Bohr. The motion of the electrons must be confined to some region by means of a boundary wall, and the electrons near the wall describe a succession of circular arcs, repeatedly bouncing on the wall, and slowly creeping round it in the direction opposite to that of the uninterrupted circles; when the moment of these electrons is taken into account, it exactly cancels out that due to the free circles. In Landau's work it is of course necessary to consider the boundary, but he shows how allowance is to be made for it by an appropriate process. The complete justification is rather subtle, and so it may be worth considering a special case, admitting of exact solution, which takes the boundary into account, and so makes it possible to follow more closely the analogy between the classical and quantum problems. With regard to the general case with a boundary wall of any type, we shall only observe that the different results arise, because in the wave problem ψ must vanish at the bounding “potential wall,” and so will be small near it; this upsets the balance of the electric current near the wall, and yields the magnetic moment.