To explore the synthesis and characterization of hydroxo-bridged Dy(III) dimers using C-H activation.
Synthesis of Dy(III) dimers
Utilization of crown ethers
C-H activation with Me3NO
Characterization of resulting complexes
Successful synthesis of hydroxo-bridged Dy(III) dimers
Demonstrated oxygen-atom transfer reactions
Illustrated the potential for new organometallic complexes through this method.
Abstract
Me3NO is well known to undergo oxygen-atom transfer reaction, while the C-H activation of Me3NO with organometallic complexes is far less explored. Herein, we reported the synthesis and characterization of...
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Synthesis of hydroxo-bridged Dy(III) dimers supported by crown ethers through C-H activation and oxygen-atom transfer of Me3NO | Synapse