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May 1, 20260 citations

Potassium tert-Butoxide Promoted Proton Transfer-Electron Transfer in Aerobic C(sp3)-H Hydroxylations.

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CLChangming LiHZHao ZhuQPQian Peng

Key Points

  • The central aim is to explore how potassium tert-butoxide facilitates proton transfer and electron transfer in aerobic reactions.
  • Theoretical analysis of the A-PTET mechanism
  • Investigation of radical intermediates
  • Assessment of aerobic C(sp3)-H hydroxylation processes.
  • Establishment of a theoretical foundation for the A-PTET mechanism.
  • Identification of radical species formed during the reaction.
  • Implications for the use of alkali-metal reagents in other reactions.

Abstract

cations stabilizes radical intermediates that induce the single electron transfer in the A-PTET mechanism, leading to the experimentally observed radical species. This study establishes a theoretical foundation for the development of aerobic reactions, and the A-PTET mechanism may extend to other reactions based on new insights into alkali-metal reagents.

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Cite This Study

Li et al. (2026) studied this question.

synapsesocial.com/papers/69f443e8967e944ac5566fd9https://doi.org/10.1021/acs.inorgchem.6c00906
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