Reveals a mechanism for aerobic C-H hydroxylations, suggesting new pathways for alkali-metal reagent applications.
cations stabilizes radical intermediates that induce the single electron transfer in the A-PTET mechanism, leading to the experimentally observed radical species. This study establishes a theoretical foundation for the development of aerobic reactions, and the A-PTET mechanism may extend to other reactions based on new insights into alkali-metal reagents.
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Li et al. (2026) studied this question.
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