The present study investigates the hydrothermal synthesis of undoped talc and talc doped with Mn 2+ and Ni 2+ cations, to probe the effectiveness on stoneware tiles sintering. Undoped, Mn- and Ni-doped talc samples were synthesized at constant pressure (2 kbar) and reaction time (160 h), under different hydrothermal conditions (temperatures of 300 °C and 650 °C, pH values of 5 and 7). Characterization techniques including Powder X-Ray Diffraction (PXRD), Scanning and Transmission Electron Microscopy coupled with Energy Dispersive Spectroscopy (SEM/EDS, TEM/EDS), Differential Scanning Calorimetry (DSC), and micro-Raman Spectroscopy (μR) were employed to analyse the starting materials, synthesized products as well as stoneware tiles. The study revealed a direct correlation between the amount of NiO in the initial mixture and the presence of Ni-dopant in the resulting talc, yielding a full substitution of Mg 2+ by Ni 2+ and the consequent formation of Ni 3 Si 4 O 10 (OH) 2 . However, in the same experimental conditions, the formation of Mn 3 Si 4 O 10 (OH) 2 is not achieved. Indeed, a saturation point for Mn 2+ doping in talc has been identified, and its nature will be discussed. Furthermore, undoped-talc, Mn doped talc and Ni-talc have all been employed for the sintering of stoneware tiles. This present study demonstrates that Mn- and Ni-doped synthetic talc act as highly effective fluxing agents in stoneware tile bodies. Their addition promotes a more rapid consumption of crystalline phases, specifically albite, at lower firing temperatures compared to undoped talc. Notably, Mn 2+ -doping (even at low concentration of dopant) exhibits a more pronounced effect than Ni-doping. This process may offer a direct pathway to substantial energy and cost savings in industrial ceramic production. • Talc doped with Mn and Ni synthesized via hydrothermal methods. • Solid solutions of Mg 3-x Si 4 O 10 (OH) 2 -Ni x Si 4 O 10 (OH) 2 successfully obtained for x = 0 to 3. • Maximum doping of Mn in Talc found to be (Mg 2 Mn)Si 4 O 10 (OH) 2. • Different thermal behaviours and Raman spectral signatures observed between pure and doped talc. • Mn- and Ni-doped talcs act as fluxing agents, enabling significant reduction in stoneware sintering temperature.
Bloise et al. (Fri,) studied this question.