What question did this study set out to answer?

The aim is to report previously unreported lanthanide tris(acethylacetonate) complexes and study their properties.

May 14, 2026New Journal of Chemistry0 citations

Filling in the Gaps: the Last Unreported Mononuclear Lanthanide tris-Acethylacetonates with 1,10-Phenanthroline for Revealing Structural Trends and Studying the Dynamic Magnetic Properties

MBMikhail E. BuzoverovNS Kurnakova Institute of General and Inorganic Chemistry AGAndrey V. GavrikovNS Kurnakova Institute of General and Inorganic Chemistry KBKonstantin A. BabeshkinNS Kurnakova Institute of General and Inorganic Chemistry

Key Points

The aim is to report previously unreported lanthanide tris(acethylacetonate) complexes and study their properties.
Synthesis of lanthanide tris(acethylacetonate) complexes with 1,10-phenanthroline
Characterization of complexes formed by Nd3+, Ho3+, and Tm3+
Analysis of structural and magnetic properties
Successful formation of square antiprismatic lanthanide complexes with identified magnetic properties
Revealed structural trends among Nd3+, Ho3+, and Tm3+ complexes
Insights into the dynamic magnetic behavior of these complexes

Abstract

We prepared and studied the last of previously unknown members of square antiprismatic lanthanide tris(acethylacetonate) complexes with 1,10-phenanthroline, namely Ln(acac)3(phen) ones formed by Nd3+ (Nd), Ho3+ (Ho) and Tm3+ (Tm)...

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