Chain and Ring Phosphorus Compounds—Analogies between Phosphorus and Carbon Chemistry

Abstract Up to about 15 years ago compounds with a skeleton of phosphorus chains or rings were regarded as “exotic” in the field of nonmetal chemistry. Aside from a number of examples of molecules with two P atoms directly bonded to each other and a few sporadically discovered monocyclic ring compounds, only solids of undefined composition and structure were known. Since then the state of our knowledge in this sector has made considerable progress: between PH 3 and its derivatives on the one hand, and the high‐molecular modifications of elementary phosphorus on the other, an unexpected variety of well defined compounds have been discovered, showing many similarities to the analogous compounds of carbon. However, surprises can still occur even with “small” phosphorus‐containing molecules, as shown by the likewise recently discovered field of phosphorus three‐membered ring compounds.