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May 15, 2026Dalton Transactions0 citations

LDH-mediated interfacial redox formation of phyllomanganate from KMnO₄: mechanistic insights and subsequent fluorination pathways

ARAbderraouf RouagSHSarah HennequartRPregis porhiel

Key Points

  • This research investigates the mechanisms by which layered double hydroxides facilitate redox reactions with potassium permanganate to form phyllomanganate.
  • Utilized layered double hydroxides with 3d metal cations (Co²⁺, Cu²⁺, Fe³⁺) contacted with potassium permanganate solution.
  • Analyzed the resulting chemical composition and formation pathways under various conditions.
  • Demonstrated successful formation of phyllomanganate through interfacial redox reactions.
  • Identified distinct fluorination pathways following the redox process.

Abstract

Thanks to their versatile chemical composition, layered double hydroxides (LDH) containing only 3d ions as intralamellar cations (Co²⁺, Cu²⁺, and Fe³⁺), when contacted with a potassium permanganate solution, lead to...

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Cite This Study

Rouag et al. (2026) studied this question.

synapsesocial.com/papers/6a06b81ce7dec685947aa9aehttps://doi.org/10.1039/d6dt00203j
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